The chemistry of C-H bond activation on diamond.
نویسندگان
چکیده
The surface of hydrogen-terminated diamond resembles a solid hydrocarbon substrate. Interestingly, the C-H bonds on the diamond surface are not as unreactive as that of saturated hydrocarbon molecules owing to its unique surface electronic properties. The invention of C-H bond activation and C-C coupling reactions on the diamond surface allows chemists to develop powerful chemical transistors, biosensors, and photovoltaic cells on the diamond platform.
منابع مشابه
The effect of some mono and bivalent metal cations on the individual hydrogen bond energies in A−T and G−C base pairs
The effect of interactions of various Ia and IIa cations with two positions of the adenine-thymine (A−T) and guanine-cytosine (G−C) base pairs on the geometries and individual hydrogen bond (HB) energies have been investigated by using the atoms in molecules (AIM) method at the B3LYP/6-311++G(d,p) level of theory. The cations that possess higher charge/radius (q/rad) ratio make higher changes o...
متن کاملA competitive Diels-Alder/1, 3-dipolar cycloaddition reaction of1-H-imidazole 3-oxide toward sulfonyl methane. A DFT study on the energetic and regioselectivity
The dual diene/1,3-dipolar character of 1-H-imidazole 3-oxide, HIO 1, allows this compound toparticipate in a competitive Diels-Alder (DA)/1,3-dipolar cycloaddition (13DC) reaction toward C=Sdouble bond of the electro-deficient sulfonyl methane SFM 2. The B3LYP/6-311++G(d,p) calculatedrelative Gibbs free energies indicate that among the studied 13DC and DA reactions, former iscompletely preferr...
متن کاملتأثیر کارایی فرزهای الماسی بر استحکام باند کامپوزیت به عاج در سیستم‌های باندینگ مختلف
Background and Aim: As composite-dentin bond strength is affected by cavity preparation and the bond strength of composite resin to new and used bur prepared dentin has not yet been evaluated, this study evaluated the effects of cutting dentin with different cutting efficacy (new and used) of burs on composite-dentin shear bond strength using self-etching primer bonding system and total etching...
متن کاملH2 Elimination and C-C Bond Cleavage of Propene: A Theoretical Research
Propene dissociation channels were characterized by ab initio CCSD(T)/6-311++g(d,p) calculations. Inthis work the detailed mechanism of propene dissociation to C2H4+CH2, C2H2+H+CH3, C2H2+CH4 andC3H3+H2+H have been investigated. According to our calculations, ten fragments can be classified intofive dissociated channels. Our results point out that two mechanisms come into play in the H2 eliminat...
متن کاملEffect of Er: YAG laser, diamond bur and sandblasting on the microtensile bond strength of the composite to noncarious cervical lesions
Background and Aims: Restoration of non-carious cervical lesions (NCCLs) is challenging due to the difficulty of adhesion of dental tissues. The aim of this study was to investigate the effects of three methods of surface treatments using diamond bur, Er: YAG laser and sandblasting on the microtensile bond strength of resin composite to the noncarious dentin in cervical lesions. Materials and ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemistry, an Asian journal
دوره 5 7 شماره
صفحات -
تاریخ انتشار 2010